Locating Tetrahedral and Octahedral Voids Essay

The sozzled packed structures have both octahedral and tetrahedral voids. In a ccp structure, there is 1 octahedral void in the tenderness of the body and 12 octahedral void on the edges. Each one of which is common to four other unit cells. Thus, in cubic close packed structure.Octahedral voids in the centre of the cube =1Effective exit of octahedral voids located at the 12 edge of = 12 1/4 = 3 Total take of octahedral voids = 4In ccp structure, there ar 8 tetrahedral voids. In close packed structure, there atomic number 18 eight spheres in the corners of the unit cell and each sphere is in contact with three groups well-favored rise to eight tetrahedral voidsCircles labelled T re bear the centers of the tetrahedral interstices in the ccp arrangement of anions. The unit cell owns 8 tetrahedral sites. Circles labelled O represent centers of the octahedral interstices in the ccp arrangement of anions (fcc unit cell). The cell owns 4 octahedral sites.Illustration 16. In a soli d, oxide ions are arranged in ccp. Cations A exact one sixth of the tetrahedral voids and cations B occupy one third of the octahedral voids. What is the formula of the compound?Solution In ccp with each oxide there would be 2 tetrahedral voids and one octahedral voids 1/3rd octahedral voids is occupied by B and 1/6th tetrahedral void by A. Therefore the compound can beIllustration 17. In a crystalline solid, having formula AB2O4, oxide ions are arranged in cubic close packed lattice while cations A are present in tetrahedral voids and cations B are present in octahedral voids .